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Overview

General comment

Not stated

Technology
Direct fluorination of tungsten metal with elemental fluorine
Geography
Global

System boundary

System boundary - Tungsten hexafluoride (WF6)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Tungsten hexafluoride (WF6)DECLARED BOUNDARYGate-to-gate WF6 synthesis and tungstenreduction; the fluorine feed carries its ownproduction burden through the linkedfluorine dataset, so it is not charged againhereENTERING FLOWSElectricityWaterMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTTungsten hexafluorideNot stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

Download this figure (SVG)

Data quality and references

Composite DQI 1.7 Very good
Reliability
2.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Industrial-chemistry reference works on tungsten for the direct-fluorination route, tungsten deposition literature for the purity specification, and stoichiometric calculation over the stated reaction; the fluorine feed comes from a linked production dataset
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • Stoichiometric calculation
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
  • Tungsten CVD literature

Technosphere inputs

8 flows. Quantities are not published; they ship with the dataset on Circa.

Tungsten metal Materialkg · -4.6% / +7.7%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Background data
proxy-mapped
Background dataset
tungsten concentrate
Notes
Tungsten metal powder fed to the fluorination reactor. Reducing the oxide to metal is inside this dataset's boundary and is inventoried by the reduction electricity and hydrogen rows. Making that oxide from the concentrate the row links is not: see the proxy note.
Uncertainty
-4.6% / +7.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Hydrogen (tungsten reduction) Materialkg · -0% / +100.9%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Background data
ecoinvent 3.12
Background dataset
hydrogen
Notes
Reducing agent for the oxide-to-metal step. The water vapour the reduction produces is not separately inventoried.
Uncertainty
-0% / +100.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Hydrated lime (wastewater treatment) Materialkg · -50% / +87.9%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Background data
proxy-mapped
Background dataset
calcium carbonate, precipitated
Notes
Precipitant for the fluoride in the scrubber blowdown. It supplies the calcium in the calcium fluoride sludge this dataset ships.
Uncertainty
-50% / +87.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Elemental fluorine Materialkg · -7.1% / +9.5%
Derivation basis
  • Quantity from the formulation/production-route recipe; upstream life cycle provenance is carried by the linked upstream unit process (see the technosphere reference)

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Upstream REEL dataset
Fluorine (F2)
Background dataset
Modelled by REEL; see the upstream dataset above.
Uncertainty
-7.1% / +9.5% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, W metal reduction, Global (GLO) ElectricitykWh · -20% / +50%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Furnace duty for the hydrogen reduction of tungsten oxide to metal. The hydrogen this step consumes is bought on the input side.
Uncertainty
-20% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, WF6 synthesis, Global (GLO) ElectricitykWh · ±50%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Reactor heating, gas handling. Reaction is exothermic
Uncertainty
±50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, purification, Global (GLO) ElectricitykWh · -40% / +60%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Fractional distillation to ppb purity
Uncertainty
-40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · -20% / +60%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-20% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L

Outputs and waste

Wastewater to treatment WastewaterL · -25% / +50%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-25% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Off-spec WOF4 product Solid wasteg · -50% / +100%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Background data
ecoinvent 3.12 treatment route
Background dataset
Recycle or tungsten recovery
Notes
Oxygen-containing tungsten oxyfluoride separated during distillation. It is an inorganic tungsten compound, valuable enough to be returned to the reactor or sent for tungsten reclaim rather than discarded. ecoinvent 3.12 publishes no tungsten-scrap or tungsten-reclamation market, so the row is linked to a generic metal-bearing sludge recovery service and that substitution is declared on the row: what the link represents is the handling of a metal-bearing residue by a recovery smelter, not any tungsten content, and a reader must not take it as a supply of secondary tungsten. Under the recyclable-byproduct cut-off convention the reclaim burden belongs to the next product system and no credit is taken here. The missing metal-specific dataset is a declared gap, not an instruction to substitute a disposal route.
Uncertainty
-50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Calcium fluoride sludge Solid wasteg · -50% / +87.2%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of inert waste, sanitary landfill
Notes
Precipitated from the fluoride in the treated wastewater; the calcium comes from the hydrated-lime input row.
Uncertainty
-50% / +87.2% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g

Emissions to air

3 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Tungsten hexafluoride (fugitive) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
  • No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Compartment
Air (non-urban air or from high stacks)
Formula
WF6
CAS number
7783-82-6
ecoinvent 3.12 elementary flow
Not stated
Notes
Minor fugitive losses; high product value minimizes losses
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Hydrogen fluoride Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Compartment
Air (non-urban air or from high stacks)
Formula
HF
CAS number
7664-39-3
ecoinvent 3.12 elementary flow
Hydrogen fluoride
Notes
Fugitive from F2 production and handling
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Fluorine Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Compartment
Air (non-urban air or from high stacks)
Formula
F2
CAS number
7782-41-4
ecoinvent 3.12 elementary flow
Fluorine
Notes
Unreacted F2; highly reactive
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

2 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Fluoride ion Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Compartment
Water (surface water)
Formula
F-
CAS number
16984-48-8
ecoinvent 3.12 elementary flow
Fluoride
Notes
Dissolved fluoride remaining in the scrubber blowdown after lime precipitation. The bulk of the captured fluoride leaves as the calcium fluoride sludge instead.
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Tungsten traces Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
Compartment
Water (surface water)
Formula
W
CAS number
7440-33-7
ecoinvent 3.12 elementary flow
Tungsten
Notes
Trace tungsten in wastewater
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (4)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • The tungsten metal input is linked to the ecoinvent tungsten CONCENTRATE market one-for-one on contained metal. Commercial concentrate is roughly half contained tungsten, so the upstream burden of that row is understated by about a factor of two.
  • The same link also skips a stage. The linked product is an ore concentrate, but the reduction this dataset counts starts from tungsten oxide, and the roasting or digestion, ammonium paratungstate and calcination steps in between are carried by neither the linked dataset nor this one. There is no oxide feed row on this dataset for that reason.
  • The tungsten lost at the conversion efficiency this route states is not carried by any output flow.
  • The water vapour produced when tungsten oxide is reduced to metal is not inventoried.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate WF6 synthesis and tungsten reduction; the fluorine feed carries its own production burden through the linked fluorine dataset, so it is not charged again here

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol