Overview
- Technology
- Direct fluorination of tungsten metal with elemental fluorine
- Geography
- Global
System boundary
The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.
Data quality and references
Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.
- Sampling procedure
- Industrial-chemistry reference works on tungsten for the direct-fluorination route, tungsten deposition literature for the purity specification, and stoichiometric calculation over the stated reaction; the fluorine feed comes from a linked production dataset
- Coverage status
- Partial
- Pedigree-scored source files
- Not stated
- Dataset sources
-
- Stoichiometric calculation
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Tungsten CVD literature
Technosphere inputs
8 flows. Quantities are not published; they ship with the dataset on Circa.
Tungsten metal Materialkg · -4.6% / +7.7%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Background data
- proxy-mapped
- Background dataset
- tungsten concentrate
- Notes
- Tungsten metal powder fed to the fluorination reactor. Reducing the oxide to metal is inside this dataset's boundary and is inventoried by the reduction electricity and hydrogen rows. Making that oxide from the concentrate the row links is not: see the proxy note.
- Uncertainty
- -4.6% / +7.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Hydrogen (tungsten reduction) Materialkg · -0% / +100.9%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Background data
- ecoinvent 3.12
- Background dataset
- hydrogen
- Notes
- Reducing agent for the oxide-to-metal step. The water vapour the reduction produces is not separately inventoried.
- Uncertainty
- -0% / +100.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Hydrated lime (wastewater treatment) Materialkg · -50% / +87.9%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Background data
- proxy-mapped
- Background dataset
- calcium carbonate, precipitated
- Notes
- Precipitant for the fluoride in the scrubber blowdown. It supplies the calcium in the calcium fluoride sludge this dataset ships.
- Uncertainty
- -50% / +87.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Elemental fluorine Materialkg · -7.1% / +9.5%
- Derivation basis
-
- Quantity from the formulation/production-route recipe; upstream life cycle provenance is carried by the linked upstream unit process (see the technosphere reference)
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Upstream REEL dataset
- Fluorine (F2)
- Background dataset
- Modelled by REEL; see the upstream dataset above.
- Uncertainty
- -7.1% / +9.5% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Electricity, W metal reduction, Global (GLO) ElectricitykWh · -20% / +50%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Furnace duty for the hydrogen reduction of tungsten oxide to metal. The hydrogen this step consumes is bought on the input side.
- Uncertainty
- -20% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, WF6 synthesis, Global (GLO) ElectricitykWh · ±50%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Reactor heating, gas handling. Reaction is exothermic
- Uncertainty
- ±50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, purification, Global (GLO) ElectricitykWh · -40% / +60%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Fractional distillation to ppb purity
- Uncertainty
- -40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Fresh water WaterL · -20% / +60%
- Derivation basis
-
- Water demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- tap water
- Uncertainty
- -20% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Outputs and waste
Wastewater to treatment WastewaterL · -25% / +50%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Background data
- carried, no background dataset
- Background dataset
- wastewater, average
- Uncertainty
- -25% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Off-spec WOF4 product Solid wasteg · -50% / +100%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- Recycle or tungsten recovery
- Notes
- Oxygen-containing tungsten oxyfluoride separated during distillation. It is an inorganic tungsten compound, valuable enough to be returned to the reactor or sent for tungsten reclaim rather than discarded. ecoinvent 3.12 publishes no tungsten-scrap or tungsten-reclamation market, so the row is linked to a generic metal-bearing sludge recovery service and that substitution is declared on the row: what the link represents is the handling of a metal-bearing residue by a recovery smelter, not any tungsten content, and a reader must not take it as a supply of secondary tungsten. Under the recyclable-byproduct cut-off convention the reclaim burden belongs to the next product system and no credit is taken here. The missing metal-specific dataset is a declared gap, not an instruction to substitute a disposal route.
- Uncertainty
- -50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Calcium fluoride sludge Solid wasteg · -50% / +87.2%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of inert waste, sanitary landfill
- Notes
- Precipitated from the fluoride in the treated wastewater; the calcium comes from the hydrated-lime input row.
- Uncertainty
- -50% / +87.2% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Emissions to air
3 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Tungsten hexafluoride (fugitive) Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
- No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- WF6
- CAS number
- 7783-82-6
- ecoinvent 3.12 elementary flow
- Not stated
- Notes
- Minor fugitive losses; high product value minimizes losses
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Hydrogen fluoride Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- HF
- CAS number
- 7664-39-3
- ecoinvent 3.12 elementary flow
- Hydrogen fluoride
- Notes
- Fugitive from F2 production and handling
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Fluorine Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- F2
- CAS number
- 7782-41-4
- ecoinvent 3.12 elementary flow
- Fluorine
- Notes
- Unreacted F2; highly reactive
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Emissions to water
2 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Fluoride ion Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Compartment
- Water (surface water)
- Formula
- F-
- CAS number
- 16984-48-8
- ecoinvent 3.12 elementary flow
- Fluoride
- Notes
- Dissolved fluoride remaining in the scrubber blowdown after lime precipitation. The bulk of the captured fluoride leaves as the calcium fluoride sludge instead.
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Tungsten traces Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Tungsten and Tungsten Alloys
- Compartment
- Water (surface water)
- Formula
- W
- CAS number
- 7440-33-7
- ecoinvent 3.12 elementary flow
- Tungsten
- Notes
- Trace tungsten in wastewater
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Flows not quantified
No flows are recorded for this dataset without a quantity.
Limitations and unquantified flows (4)
Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.
- The tungsten metal input is linked to the ecoinvent tungsten CONCENTRATE market one-for-one on contained metal. Commercial concentrate is roughly half contained tungsten, so the upstream burden of that row is understated by about a factor of two.
- The same link also skips a stage. The linked product is an ore concentrate, but the reduction this dataset counts starts from tungsten oxide, and the roasting or digestion, ammonium paratungstate and calcination steps in between are carried by neither the linked dataset nor this one. There is no oxide feed row on this dataset for that reason.
- The tungsten lost at the conversion efficiency this route states is not carried by any output flow.
- The water vapour produced when tungsten oxide is reduced to metal is not inventoried.
The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.
Boundary declared by this dataset
Gate-to-gate WF6 synthesis and tungsten reduction; the fluorine feed carries its own production burden through the linked fluorine dataset, so it is not charged again here
Database-wide boundary policy — applies to every REEL dataset
These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.
- Use phase
- Product operation is outside the cradle-to-gate scope.
- End-of-life treatment
- Recycling and disposal are outside the cradle-to-gate scope.
- Distribution and retail
- The gate is a finished component ready for integration into a higher-level assembly.
- Inbound transport of raw materials
- Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
- Returnable shipping containers
- Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
- Photomask fabrication
- A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
- Employee transport, administration and R&D overhead
- Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
- Capital goods
- Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
- Precious metal recovery credits
- Scrap recovery credits for precious metals are excluded pending data availability.
- Wafer reclaim
- Test wafers and scrap are outside the system boundary.
Inside the boundary, linked rather than modelled
- Silicon ingot growth and wafer slicing
- Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
- Freight between production stages
- Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.
Cut-off criteria
A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.
Included regardless of the cut-off
- Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
- Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
- Volatile organics (photoresist solvents, PGMEA) - air quality
- Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
- Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol
Not stated