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Overview

General comment

Not stated

Technology
Alkyl exchange reaction with KF-assisted separation
Geography
Global

System boundary

System boundary - Trimethylindium (In(CH3)3)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Trimethylindium (In(CH3)3)DECLARED BOUNDARYGate-to-gate TMIn synthesis from InCl3 +TMAlENTERING FLOWSElectricityWaterProcess gasesMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTTrimethylindiumNot stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

Download this figure (SVG)

Data quality and references

Composite DQI 1.7 Very good
Reliability
2.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Production and high-purity synthesis patents for the alkyl-exchange route, a peer-reviewed life cycle study of III-V precursors for energy demand, and stoichiometric calculation over the stated reaction
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • US Patent 5756786A - Method of synthesis for high purity TMIn
  • EP Patent - High purity TMIn production
  • Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287
  • Stoichiometric calculation

Technosphere inputs

8 flows. Quantities are not published; they ship with the dataset on Circa.

Indium trichloride Materialkg · -34.9% / +17.9%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
Background data
proxy-mapped
Background dataset
indium
Notes
Made from In metal + HCl or Cl2
Uncertainty
-34.9% / +17.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Trimethylaluminum Materialkg · -35.1% / +20.2%
Derivation basis
  • Quantity from the formulation/production-route recipe; upstream life cycle provenance is carried by the linked upstream unit process (see the technosphere reference)

The sources for this row are listed below.

Source citations (dataset-level)
Upstream REEL dataset
Trimethylaluminum (Al(CH3)3)
Background dataset
Modelled by REEL; see the upstream dataset above.
Notes
Alkylating agent; excess ensures complete reaction
Uncertainty
-35.1% / +20.2% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Potassium fluoride Materialkg · -16.7% / +33.3%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
Background data
proxy-mapped
Background dataset
sodium fluoride
Notes
Complexing agent; forms the potassium fluoroaluminate salt and KCl
Uncertainty
-16.7% / +33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Squalane (solvent) Materialkg · ±33.3%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
Background data
proxy-mapped
Background dataset
paraffin
Notes
High-boiling alkane suspension medium, recovered between batches. This row is the non-recoverable make-up, which is what the process consumes.
Uncertainty
±33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, Global (GLO) ElectricitykWh · ±21.4%
Source citations
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Heating, vacuum sublimation, purification
Uncertainty
±21.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · -40% / +60%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Nitrogen (N2) Process gaskg · -33.3% / +50%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
nitrogen, liquid
Notes
Inert atmosphere for pyrophoric handling
Uncertainty
-33.3% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Argon (Ar) Process gaskg · -50% / +100%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
argon, liquid
Notes
Purging and blanketing
Uncertainty
-50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg

Outputs and waste

Wastewater to treatment WastewaterL · -62.4% / +166.6%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-62.4% / +166.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Al/K/Cl/F complex residue Solid wasteg · -16.7% / +11.4%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, underground deposit
Notes
Main byproduct: the potassium fluoroaluminate salt and the potassium chloride the complexing agent forms, leaving together as one bottoms stream. The quantity is a stoichiometric figure on the reaction route the production patents state, taken on the assumption that all of the complexing agent bought is converted; it is not a measured residue. What an operating plant's bottoms actually contain is not reported by any public source and is a declared gap. An inorganic salt residue, routed to controlled inorganic disposal.
Uncertainty
-16.7% / +11.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Indium-containing residue Solid wasteg · ±25%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
Background data
ecoinvent 3.12 treatment route
Background dataset
Indium recovery
Notes
Sublimation bottoms carrying unrecovered indium. Indium is valuable enough that this stream is sold to a reclaimer rather than disposed of. ecoinvent 3.12 publishes no indium-scrap or indium-reclamation market, so the row is linked to a generic metal-bearing sludge recovery service and that substitution is declared on the row: what the link represents is the handling of a metal-bearing residue by a recovery smelter, not any indium content, and a reader must not take it as a supply of secondary indium. It is not a landfill or incineration route. Under the recyclable-byproduct cut-off convention the reclaim burden belongs to the next product system and no credit is taken here. The missing metal-specific dataset remains a declared gap.
Uncertainty
±25% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Spent squalane Solid wasteg · ±33.3%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
Non-recoverable fraction of the squalane charge, equal to the make-up bought on the input side.
Uncertainty
±33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g

Emissions to air

2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Trimethylindium Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
  • No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link

No source is attached to this row.

Source citations
Not stated
Compartment
Air (non-urban air or from high stacks)
Formula
In(CH3)3
CAS number
3385-78-2
ecoinvent 3.12 elementary flow
Not stated
Notes
Pyrophoric; sublimation losses partially captured
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Volatile organic compounds (VOC) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
Compartment
Air (non-urban air or from high stacks)
ecoinvent 3.12 elementary flow
NMVOC, non-methane volatile organic compounds
Notes
From squalane and minor organics
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

No emissions to water are recorded at this level.

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (3)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • The reaction-salt residue is booked at what the complexing agent bought can build under the reaction the production patents state, on the assumption that the agent bought is completely converted. That is a stoichiometric figure, not a measured residue. What the bottoms of an operating plant actually contain - how far conversion really goes, and in what proportions the salts leave - is not reported by any public source, so the composition of this stream is a declared gap.
  • The indium content of the reclaim residue is not measured. The inventory adopts a documented figure just inside the bound the process indium balance sets, so the indium closes under that stated assumption rather than on evidence.
  • The cooling-tower blowdown is now carried as a wastewater flow, but its dissolved load is not. The loop is non-contact and the synthesis is anhydrous, so nothing from the reaction reaches it; what the blowdown actually carries is the make-up water's own minerals concentrated up, plus the tower's biocide and scale inhibitor. Those depend on the site's intake water quality, which a global-average dataset cannot state, so the volume ships and the load does not.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate TMIn synthesis from InCl3 + TMAl

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol