Overview
- Technology
- Alkyl exchange reaction with KF-assisted separation
- Geography
- Global
System boundary
The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.
Data quality and references
Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.
- Sampling procedure
- Production and high-purity synthesis patents for the alkyl-exchange route, a peer-reviewed life cycle study of III-V precursors for energy demand, and stoichiometric calculation over the stated reaction
- Coverage status
- Partial
- Pedigree-scored source files
- Not stated
- Dataset sources
-
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287
- Stoichiometric calculation
Technosphere inputs
8 flows. Quantities are not published; they ship with the dataset on Circa.
Indium trichloride Materialkg · -34.9% / +17.9%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- proxy-mapped
- Background dataset
- indium
- Notes
- Made from In metal + HCl or Cl2
- Uncertainty
- -34.9% / +17.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Trimethylaluminum Materialkg · -35.1% / +20.2%
- Derivation basis
-
- Quantity from the formulation/production-route recipe; upstream life cycle provenance is carried by the linked upstream unit process (see the technosphere reference)
The sources for this row are listed below.
- Source citations (dataset-level)
-
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Upstream REEL dataset
- Trimethylaluminum (Al(CH3)3)
- Background dataset
- Modelled by REEL; see the upstream dataset above.
- Notes
- Alkylating agent; excess ensures complete reaction
- Uncertainty
- -35.1% / +20.2% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Potassium fluoride Materialkg · -16.7% / +33.3%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- proxy-mapped
- Background dataset
- sodium fluoride
- Notes
- Complexing agent; forms the potassium fluoroaluminate salt and KCl
- Uncertainty
- -16.7% / +33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Squalane (solvent) Materialkg · ±33.3%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- proxy-mapped
- Background dataset
- paraffin
- Notes
- High-boiling alkane suspension medium, recovered between batches. This row is the non-recoverable make-up, which is what the process consumes.
- Uncertainty
- ±33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Electricity, Global (GLO) ElectricitykWh · ±21.4%
- Source citations
-
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Heating, vacuum sublimation, purification
- Uncertainty
- ±21.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Fresh water WaterL · -40% / +60%
- Derivation basis
-
- Water demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- tap water
- Uncertainty
- -40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Nitrogen (N2) Process gaskg · -33.3% / +50%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- nitrogen, liquid
- Notes
- Inert atmosphere for pyrophoric handling
- Uncertainty
- -33.3% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Argon (Ar) Process gaskg · -50% / +100%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- argon, liquid
- Notes
- Purging and blanketing
- Uncertainty
- -50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Outputs and waste
Wastewater to treatment WastewaterL · -62.4% / +166.6%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- carried, no background dataset
- Background dataset
- wastewater, average
- Uncertainty
- -62.4% / +166.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Al/K/Cl/F complex residue Solid wasteg · -16.7% / +11.4%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, underground deposit
- Notes
- Main byproduct: the potassium fluoroaluminate salt and the potassium chloride the complexing agent forms, leaving together as one bottoms stream. The quantity is a stoichiometric figure on the reaction route the production patents state, taken on the assumption that all of the complexing agent bought is converted; it is not a measured residue. What an operating plant's bottoms actually contain is not reported by any public source and is a declared gap. An inorganic salt residue, routed to controlled inorganic disposal.
- Uncertainty
- -16.7% / +11.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Indium-containing residue Solid wasteg · ±25%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- Indium recovery
- Notes
- Sublimation bottoms carrying unrecovered indium. Indium is valuable enough that this stream is sold to a reclaimer rather than disposed of. ecoinvent 3.12 publishes no indium-scrap or indium-reclamation market, so the row is linked to a generic metal-bearing sludge recovery service and that substitution is declared on the row: what the link represents is the handling of a metal-bearing residue by a recovery smelter, not any indium content, and a reader must not take it as a supply of secondary indium. It is not a landfill or incineration route. Under the recyclable-byproduct cut-off convention the reclaim burden belongs to the next product system and no credit is taken here. The missing metal-specific dataset remains a declared gap.
- Uncertainty
- ±25% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Spent squalane Solid wasteg · ±33.3%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- Non-recoverable fraction of the squalane charge, equal to the make-up bought on the input side.
- Uncertainty
- ±33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Emissions to air
2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Trimethylindium Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
- No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link
No source is attached to this row.
- Source citations
- Not stated
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- In(CH3)3
- CAS number
- 3385-78-2
- ecoinvent 3.12 elementary flow
- Not stated
- Notes
- Pyrophoric; sublimation losses partially captured
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Volatile organic compounds (VOC) Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- US Patent 5756786A - Method of synthesis for high purity TMIn
- EP Patent - High purity TMIn production
- Smith, B.L.; Babbitt, C.W.; Horowitz, K.; Gaustad, G.; Hubbard, S.M. (2018). Smith, B.L., Babbitt, C.W., Horowitz, K., Gaustad, G., Hubbard, S.M. (2018). "Life Cycle Assessment of III-V Precursors for Photovoltaic and Semiconductor Applications." MRS Advances 3(25), 1399-1404. doi:10.1557/adv.2018.287. MRS Advances 3(25), 1399-1404. DOI: 10.1557/adv.2018.287.
- Compartment
- Air (non-urban air or from high stacks)
- ecoinvent 3.12 elementary flow
- NMVOC, non-methane volatile organic compounds
- Notes
- From squalane and minor organics
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Emissions to water
No emissions to water are recorded at this level.
Flows not quantified
No flows are recorded for this dataset without a quantity.
Limitations and unquantified flows (3)
Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.
- The reaction-salt residue is booked at what the complexing agent bought can build under the reaction the production patents state, on the assumption that the agent bought is completely converted. That is a stoichiometric figure, not a measured residue. What the bottoms of an operating plant actually contain - how far conversion really goes, and in what proportions the salts leave - is not reported by any public source, so the composition of this stream is a declared gap.
- The indium content of the reclaim residue is not measured. The inventory adopts a documented figure just inside the bound the process indium balance sets, so the indium closes under that stated assumption rather than on evidence.
- The cooling-tower blowdown is now carried as a wastewater flow, but its dissolved load is not. The loop is non-contact and the synthesis is anhydrous, so nothing from the reaction reaches it; what the blowdown actually carries is the make-up water's own minerals concentrated up, plus the tower's biocide and scale inhibitor. Those depend on the site's intake water quality, which a global-average dataset cannot state, so the volume ships and the load does not.
The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.
Boundary declared by this dataset
Gate-to-gate TMIn synthesis from InCl3 + TMAl
Database-wide boundary policy — applies to every REEL dataset
These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.
- Use phase
- Product operation is outside the cradle-to-gate scope.
- End-of-life treatment
- Recycling and disposal are outside the cradle-to-gate scope.
- Distribution and retail
- The gate is a finished component ready for integration into a higher-level assembly.
- Inbound transport of raw materials
- Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
- Returnable shipping containers
- Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
- Photomask fabrication
- A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
- Employee transport, administration and R&D overhead
- Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
- Capital goods
- Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
- Precious metal recovery credits
- Scrap recovery credits for precious metals are excluded pending data availability.
- Wafer reclaim
- Test wafers and scrap are outside the system boundary.
Inside the boundary, linked rather than modelled
- Silicon ingot growth and wafer slicing
- Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
- Freight between production stages
- Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.
Cut-off criteria
A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.
Included regardless of the cut-off
- Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
- Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
- Volatile organics (photoresist solvents, PGMEA) - air quality
- Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
- Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol
Not stated