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Overview

General comment

Not stated

Technology
Sodium reduction of dimethylaluminum chloride
Geography
Global

System boundary

System boundary - Trimethylaluminum (Al(CH3)3)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Trimethylaluminum (Al(CH3)3)DECLARED BOUNDARYGate-to-gate TMAl synthesis from DMAC + NaENTERING FLOWSElectricityWaterProcess gasesMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTTrimethylaluminumNot stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

Download this figure (SVG)

Data quality and references

Composite DQI 1.7 Very good
Reliability
2.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
A production patent for the sodium-reduction route and industrial-chemistry reference works on aluminium alkyls, with stoichiometric calculation over the stated reaction for raw materials and yields
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
  • Stoichiometric calculation

Technosphere inputs

8 flows. Quantities are not published; they ship with the dataset on Circa.

Dimethylaluminum chloride Materialkg · -11.1% / +12.9%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
proxy-mapped
Background dataset
aluminium chloride
Notes
Made from Al + CH3Cl or Ziegler process
Uncertainty
-11.1% / +12.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Sodium metal Materialkg · -11.1% / +20.4%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
ecoinvent 3.12
Background dataset
sodium
Notes
Dispersed in oil for controlled reaction
Uncertainty
-11.1% / +20.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Mineral oil Materialkg · ±33.3%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
proxy-mapped
Background dataset
lubricating oil
Notes
Sodium dispersion medium, recovered between batches. This row is the non-recoverable make-up, which is what the process consumes.
Uncertainty
±33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Sodium fluoride (catalyst) Materialkg · -60% / +100%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
ecoinvent 3.12
Background dataset
sodium fluoride
Notes
Catalyst to improve yield
Uncertainty
-60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, Global (GLO) ElectricitykWh · ±21.4%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Heating, agitation, distillation
Uncertainty
±21.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · ±50%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
±50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Nitrogen (N2) Process gaskg · -40% / +50%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
nitrogen, liquid
Notes
Inert atmosphere for extreme pyrophoric handling
Uncertainty
-40% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Argon (Ar) Process gaskg · -60% / +100%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
argon, liquid
Notes
Purging and blanketing
Uncertainty
-60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg

Outputs and waste

Wastewater to treatment WastewaterL · -68.8% / +150%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-68.8% / +150% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Sodium chloride (contaminated) Solid wasteg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, underground deposit
Notes
Reaction salt, contaminated with organics and with residual aluminium from the dispersion. The aluminium residue makes it water-reactive, so it does not qualify for an inert-waste landfill route, and its organic load rules out food or de-icing grades.
Uncertainty
No range defined.
Unit
g
Aluminum residue Solid wasteg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, underground deposit
Notes
Metallic aluminium liberated by the reduction, pyrophoric and contaminated. Routed to controlled disposal after passivation; it is an inorganic metal residue, not an incinerable organic.
Uncertainty
No range defined.
Unit
g
Spent mineral oil Solid wasteg · ±33.3%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
Non-recoverable fraction of the oil charge, equal to the make-up bought on the input side.
Uncertainty
±33.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g

Emissions to air

2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Trimethylaluminum Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
  • No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link

No source is attached to this row.

Source citations
Not stated
Compartment
Air (non-urban air or from high stacks)
Formula
Al(CH3)3
CAS number
75-24-1
ecoinvent 3.12 elementary flow
Not stated
Notes
Extremely pyrophoric; fugitives ignite and convert to Al2O3
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Volatile organic compounds (VOC) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • CA Patent 2054511A1 - Preparation of trimethylaluminum
  • Kirk-Othmer Encyclopedia - Aluminum Compounds
Compartment
Air (non-urban air or from high stacks)
ecoinvent 3.12 elementary flow
NMVOC, non-methane volatile organic compounds
Notes
From oil and minor organics
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

No emissions to water are recorded at this level.

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (3)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • About a tenth of the reagent entering the process is not converted, which is what the route's stated yield implies. That material leaves the plant in distillation bottoms and salt cake, but no public source splits it into named streams, so it is not represented as an output flow here.
  • The fluoride catalyst brings fluorine into the process that no output flow carries.
  • The cooling-tower blowdown is now carried as a wastewater flow, but its dissolved load is not. The loop is non-contact and the synthesis is anhydrous, so nothing from the reaction reaches it; what the blowdown actually carries is the make-up water's own minerals concentrated up, plus the tower's biocide and scale inhibitor. Those depend on the site's intake water quality, which a global-average dataset cannot state, so the volume ships and the load does not.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate TMAl synthesis from DMAC + Na

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol