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Overview

General comment

Not stated

Technology
Dilution of concentrated TMAH (typically 25% aqueous) to 2.38% with deionised water, filtration to particle spec, and fill
Geography
Global

System boundary

System boundary - TMAH Developer (2.38% solution) (N(CH3)4OH (aq))System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.TMAH Developer (2.38% solution) (N(CH3)4OH (aq))DECLARED BOUNDARYBlending and dilution, gate-to-gate; TMAHsynthesis is carried by the linked pure-TMAHproduction dataset and water by itsecoinvent marketENTERING FLOWSElectricityWaterMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTTMAH Developer (2.38% solution)Not stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

Download this figure (SVG)

Data quality and references

Composite DQI 1.3 Very good
Reliability
2.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
1.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Composition is definitional at the industry-standard developer concentration rather than sampled: the dissolved active ingredient links the separate TMAH production dataset and the dilution water links a mapped background market. Blending electricity, rinse water, and filter waste are declared engineering estimates with no published source.
Coverage status
Partial
Pedigree-scored source files
Not stated

Technosphere inputs

4 flows. Quantities are not published; they ship with the dataset on Circa.

Tetramethylammonium hydroxide (pure) Materialkg
Derivation basis
  • Quantity from the formulation/production-route recipe; upstream life cycle provenance is carried by the linked upstream unit process (see the technosphere reference)

No source is attached to this row.

Source citations
Not stated
Background dataset
Modelled by REEL; see the upstream dataset above.
Notes
Pure-TMAH content; the production burden is carried by the linked pure-TMAH dataset
Uncertainty
No range defined.
Unit
kg
Water, deionised Materialkg
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
water, deionised
Notes
Dilution water is part of the purchased product (produced at the chemical supplier, not fab UPW)
Uncertainty
No range defined.
Unit
kg
Electricity, Global (GLO) ElectricitykWh · -50% / +200%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Mixing, sub-0.1 um filtration, particle/metal QC, fill. Ambient-temperature dilution; no reaction or thermal step
Uncertainty
-50% / +200% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · -50% / +150%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-50% / +150% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L

Outputs and waste

Wastewater to treatment WastewaterL · -50% / +150%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-50% / +150% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Spent filter cartridges Solid wasteg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of inert waste, sanitary landfill
Notes
Polypropylene filter allocated per kilogram of product. The cartridge material this waste comes from is not bought anywhere in this dataset: no public service life or throughput was found for the filters on this route, so the discard is reported and the purchase behind it is left as a stated gap.
Uncertainty
No range defined.
Unit
g

Emissions to air

No emissions to air are recorded at this level.

Emissions to water

1 elementary flow released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Tetramethylammonium hydroxide Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Compartment
Water (surface water)
Formula
N(CH3)4OH
CAS number
75-59-2
ecoinvent 3.12 elementary flow
Tetramethyl ammonium hydroxide
Notes
Dissolved developer carried out of the blend tank by the equipment rinse. The rinse goes to on-site treatment and this dataset reports its volume separately as a transfer to that treatment, and the sources behind the dataset do not fix where in that chain the quantity reported here was measured. The treatment position is unresolved: this row states neither that the amount stayed in the treated effluent nor that it entered the treatment.; Compartment borrow, not an exact match: this water emission links to the AIR-compartment Tetramethyl ammonium hydroxide flow (non-urban air or from high stacks) because ecoinvent 3.12 publishes no water-compartment TMAH elementary flow. Substance, quantity and the authored water compartment are unchanged; only the linked flow is from the air compartment.
Uncertainty
No range defined.
Unit
g

Flows not quantified

No flows are recorded for this dataset without a quantity.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Blending and dilution, gate-to-gate; TMAH synthesis is carried by the linked pure-TMAH production dataset and water by its ecoinvent market

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol