Overview
- Technology
- Quaternization of trimethylamine followed by hydroxide exchange
- Geography
- Global
System boundary
The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.
Data quality and references
Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.
- Sampling procedure
- Quaternary-ammonium chemistry literature for the quaternization and hydroxide-exchange route, with stoichiometric calculation for the raw-material ratios. Public production data is limited, so process energy is a proxy estimate and the intermediates are linked to mapped background markets.
- Coverage status
- Partial
- Pedigree-scored source files
- Not stated
- Dataset sources
-
- Stoichiometric calculation
- Quaternary ammonium chemistry literature
- Proxy estimate
Technosphere inputs
8 flows. Quantities are not published; they ship with the dataset on Circa.
Trimethylamine Materialkg · -9.7% / +18.1%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- trimethylamine
- Notes
- This dataset links directly to the ecoinvent 3.12 market for trimethylamine in the rest-of-world geography. It excludes separate electricity for trimethylamine synthesis because that production is already included in the linked market. The proxy decomposition below documents the synthesis route but is not included in the inventory.
- Uncertainty
- -9.7% / +18.1% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Methyl chloride Materialkg · -8.2% / +14.8%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- methyl chloride
- Notes
- This dataset links directly to the ecoinvent 3.12 market for methyl chloride in the rest-of-world geography. It excludes separate electricity for methyl chloride synthesis because that production is already included in the linked market. The proxy decomposition below documents the synthesis route but is not included in the inventory.
- Uncertainty
- -8.2% / +14.8% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Sodium hydroxide Materialkg · -12% / +20%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- sodium hydroxide, without water, in 50% solution state
- Notes
- Available in ecoinvent; for hydroxide exchange
- Uncertainty
- -12% / +20% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Electricity, quaternization, Global (GLO) ElectricitykWh · -33.3% / +66.7%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Quaternization reaction
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, hydroxide exchange, Global (GLO) ElectricitykWh · -33.3% / +66.7%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Ion exchange or electrolysis
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, purification, Global (GLO) ElectricitykWh · -50% / +100%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Electronic grade purification. Ion exchange, electrodialysis
- Uncertainty
- -50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Steam Thermalkg · -33.3% / +66.7%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- steam, in chemical industry
- Notes
- Reactor heating, distillation, drying
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Fresh water WaterL · -35.1% / +51.4%
- Derivation basis
-
- Water demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- tap water
- Uncertainty
- -35.1% / +51.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Outputs and waste
Wastewater to treatment WastewaterL · -42.9% / +57.1%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- carried, no background dataset
- Background dataset
- wastewater, average
- Uncertainty
- -42.9% / +57.1% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Sodium chloride (impure) Solid wasteg · -15.5% / +9.9%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of inert waste, sanitary landfill
- Notes
- Reaction salt from the hydroxide-exchange step, carrying trace organics that rule out resale.
- Uncertainty
- -15.5% / +9.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Spent ion exchange resin Solid wasteg · -50% / +100%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- From the purification step. The resin this waste comes from is not bought anywhere in this dataset: ion exchange resin is regenerated many times before it is discarded and no public figure was found for how many cycles this route runs, so the discard is reported and the purchase behind it is left as a stated gap.
- Uncertainty
- -50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Distillation residue Solid wasteg · -46.7% / +100%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- Heavy organics from purification
- Uncertainty
- -46.7% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Purge and neutralisation residue to treatment Solid wasteg · -37.9% / +55.3%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- Unreacted amine, methyl chloride and caustic collected from the reactor purge and the neutralisation step. The split between species is not resolved - see the declared gap.
- Uncertainty
- -37.9% / +55.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Emissions to air
2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Trimethylamine (fugitive) Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- (CH3)3N
- CAS number
- 75-50-3
- ecoinvent 3.12 elementary flow
- Trimethylamine
- Notes
- Fishy odor; fugitive from synthesis
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Methyl chloride (fugitive) Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Compartment
- Air (unspecified)
- Formula
- CH3Cl
- CAS number
- 74-87-3
- ecoinvent 3.12 elementary flow
- Methylchloride
- Notes
- VOC; unreacted starting material
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Emissions to water
3 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Chloride ion Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Compartment
- Water (surface water)
- Formula
- Cl-
- CAS number
- 16887-00-6
- ecoinvent 3.12 elementary flow
- Chloride
- Notes
- From NaCl byproduct washing
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Sodium ion Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
No source is attached to this row.
- Source citations
- Not stated
- Compartment
- Water (surface water)
- Formula
- Na+
- CAS number
- 17341-25-2
- ecoinvent 3.12 elementary flow
- Sodium I
- Notes
- From NaCl and NaOH
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Quaternary ammonium traces Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
- No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link
No source is attached to this row.
- Source citations
- Not stated
- Compartment
- Water (surface water)
- Formula
- TMA+
- ecoinvent 3.12 elementary flow
- Not stated
- Notes
- Trace TMAH in wastewater
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Flows not quantified
No flows are recorded for this dataset without a quantity.
Limitations and unquantified flows (1)
Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.
- The purge and neutralisation residue row is not broken down by substance. It carries the declared excess of amine, methyl chloride and caustic that the product, the reaction salt and the measured emissions do not account for; no public source splits it into named species.
The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.
Boundary declared by this dataset
Gate-to-gate synthesis; proxied upstream for intermediates
Database-wide boundary policy — applies to every REEL dataset
These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.
- Use phase
- Product operation is outside the cradle-to-gate scope.
- End-of-life treatment
- Recycling and disposal are outside the cradle-to-gate scope.
- Distribution and retail
- The gate is a finished component ready for integration into a higher-level assembly.
- Inbound transport of raw materials
- Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
- Returnable shipping containers
- Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
- Photomask fabrication
- A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
- Employee transport, administration and R&D overhead
- Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
- Capital goods
- Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
- Precious metal recovery credits
- Scrap recovery credits for precious metals are excluded pending data availability.
- Wafer reclaim
- Test wafers and scrap are outside the system boundary.
Inside the boundary, linked rather than modelled
- Silicon ingot growth and wafer slicing
- Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
- Freight between production stages
- Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.
Cut-off criteria
A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.
Included regardless of the cut-off
- Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
- Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
- Volatile organics (photoresist solvents, PGMEA) - air quality
- Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
- Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol
Not stated