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Overview

General comment

Not stated

Technology
Quaternization of trimethylamine followed by hydroxide exchange
Geography
Global

System boundary

System boundary - Tetramethylammonium hydroxide (N(CH3)4OH)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Tetramethylammonium hydroxide (N(CH3)4OH)DECLARED BOUNDARYGate-to-gate synthesis; proxied upstream forintermediatesENTERING FLOWSElectricityWaterMaterialsThermalSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTTetramethylammonium hydroxideNot stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

Download this figure (SVG)

Data quality and references

Composite DQI 2.1 Good
Reliability
5.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Quaternary-ammonium chemistry literature for the quaternization and hydroxide-exchange route, with stoichiometric calculation for the raw-material ratios. Public production data is limited, so process energy is a proxy estimate and the intermediates are linked to mapped background markets.
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • Stoichiometric calculation
  • Quaternary ammonium chemistry literature
  • Proxy estimate

Technosphere inputs

8 flows. Quantities are not published; they ship with the dataset on Circa.

Trimethylamine Materialkg · -9.7% / +18.1%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
trimethylamine
Notes
This dataset links directly to the ecoinvent 3.12 market for trimethylamine in the rest-of-world geography. It excludes separate electricity for trimethylamine synthesis because that production is already included in the linked market. The proxy decomposition below documents the synthesis route but is not included in the inventory.
Uncertainty
-9.7% / +18.1% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Methyl chloride Materialkg · -8.2% / +14.8%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
methyl chloride
Notes
This dataset links directly to the ecoinvent 3.12 market for methyl chloride in the rest-of-world geography. It excludes separate electricity for methyl chloride synthesis because that production is already included in the linked market. The proxy decomposition below documents the synthesis route but is not included in the inventory.
Uncertainty
-8.2% / +14.8% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Sodium hydroxide Materialkg · -12% / +20%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
sodium hydroxide, without water, in 50% solution state
Notes
Available in ecoinvent; for hydroxide exchange
Uncertainty
-12% / +20% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, quaternization, Global (GLO) ElectricitykWh · -33.3% / +66.7%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Quaternization reaction
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, hydroxide exchange, Global (GLO) ElectricitykWh · -33.3% / +66.7%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Ion exchange or electrolysis
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, purification, Global (GLO) ElectricitykWh · -50% / +100%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Electronic grade purification. Ion exchange, electrodialysis
Uncertainty
-50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Steam Thermalkg · -33.3% / +66.7%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
steam, in chemical industry
Notes
Reactor heating, distillation, drying
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Fresh water WaterL · -35.1% / +51.4%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-35.1% / +51.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L

Outputs and waste

Wastewater to treatment WastewaterL · -42.9% / +57.1%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-42.9% / +57.1% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Sodium chloride (impure) Solid wasteg · -15.5% / +9.9%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of inert waste, sanitary landfill
Notes
Reaction salt from the hydroxide-exchange step, carrying trace organics that rule out resale.
Uncertainty
-15.5% / +9.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Spent ion exchange resin Solid wasteg · -50% / +100%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
From the purification step. The resin this waste comes from is not bought anywhere in this dataset: ion exchange resin is regenerated many times before it is discarded and no public figure was found for how many cycles this route runs, so the discard is reported and the purchase behind it is left as a stated gap.
Uncertainty
-50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Distillation residue Solid wasteg · -46.7% / +100%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
Heavy organics from purification
Uncertainty
-46.7% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Purge and neutralisation residue to treatment Solid wasteg · -37.9% / +55.3%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
Unreacted amine, methyl chloride and caustic collected from the reactor purge and the neutralisation step. The split between species is not resolved - see the declared gap.
Uncertainty
-37.9% / +55.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g

Emissions to air

2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Trimethylamine (fugitive) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Compartment
Air (non-urban air or from high stacks)
Formula
(CH3)3N
CAS number
75-50-3
ecoinvent 3.12 elementary flow
Trimethylamine
Notes
Fishy odor; fugitive from synthesis
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Methyl chloride (fugitive) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Compartment
Air (unspecified)
Formula
CH3Cl
CAS number
74-87-3
ecoinvent 3.12 elementary flow
Methylchloride
Notes
VOC; unreacted starting material
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

3 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Chloride ion Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Compartment
Water (surface water)
Formula
Cl-
CAS number
16887-00-6
ecoinvent 3.12 elementary flow
Chloride
Notes
From NaCl byproduct washing
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Sodium ion Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Compartment
Water (surface water)
Formula
Na+
CAS number
17341-25-2
ecoinvent 3.12 elementary flow
Sodium I
Notes
From NaCl and NaOH
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Quaternary ammonium traces Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
  • No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link

No source is attached to this row.

Source citations
Not stated
Compartment
Water (surface water)
Formula
TMA+
ecoinvent 3.12 elementary flow
Not stated
Notes
Trace TMAH in wastewater
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (1)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • The purge and neutralisation residue row is not broken down by substance. It carries the declared excess of amine, methyl chloride and caustic that the product, the reaction salt and the measured emissions do not account for; no public source splits it into named species.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate synthesis; proxied upstream for intermediates

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol