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Overview

General comment

Not stated

Technology
Two-step polycondensation of PMDA and ODA
Geography
Global

System boundary

System boundary - Polyimide (PMDA/ODA) ((C22H10N2O5)n)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Polyimide (PMDA/ODA) ((C22H10N2O5)n)DECLARED BOUNDARYGate-to-gate synthesis; proxied upstream formonomersENTERING FLOWSElectricityWaterMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTPolyimide (PMDA/ODA)Not stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

Download this figure (SVG)

Data quality and references

Composite DQI 2.1 Good
Reliability
5.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Published polyimide synthesis literature for the polycondensation and imidization route and a recent life cycle study of the field. Monomer ratios and condensation water are stoichiometric; process energy is a proxy estimate and the upstream monomers are represented by chemically similar proxies.
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • Stoichiometric calculation
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
  • Proxy estimate

Technosphere inputs

9 flows. Quantities are not published; they ship with the dataset on Circa.

PMDA (Pyromellitic dianhydride) Materialkg · -5% / +8.3%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Background data
proxy-mapped
Background dataset
phthalic anhydride
Notes
CarbonMinds dataset available (Fair quality); ecoinvent fallback via phthalic anhydride proxy
Uncertainty
-5% / +8.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
ODA (4,4'-Oxydianiline) Materialkg · -5.5% / +9.1%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Background data
proxy-mapped
Background dataset
aniline
Notes
Not in ecoinvent; proxied via aniline + synthesis
Uncertainty
-5.5% / +9.1% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
NMP solvent Materialkg · -50% / +100%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Background data
ecoinvent 3.12
Background dataset
N-methyl-2-pyrrolidone
Notes
Solvent for the polyamic-acid synthesis, distilled and returned to the next batch. This row is the non-recoverable make-up, which is what the process consumes.
Uncertainty
-50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, PMDA synthesis proxy, Global (GLO) ElectricitykWh · -33.3% / +66.7%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
PMDA oxidation reaction. scaled from the phthalic anhydride basis
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, ODA synthesis, Global (GLO) ElectricitykWh · -25% / +50%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
ODA multi-step synthesis + hydrogenation. Condensation + nitro reduction
Uncertainty
-25% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, PAA polymerization, Global (GLO) ElectricitykWh · -33.3% / +66.7%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Mixing, cooling, nitrogen purge. Room temperature reaction
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, thermal imidization, Global (GLO) ElectricitykWh · -33.3% / +66.7%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Heating to 300-400°C for cure. Major energy consumer; depends on batch size
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, solvent recovery, Global (GLO) ElectricitykWh · -40% / +60%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
NMP distillation and recovery
Uncertainty
-40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · -33.3% / +55.6%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-33.3% / +55.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L

Outputs and waste

Wastewater to treatment WastewaterL · -42.9% / +71.4%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-42.9% / +71.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Off-spec polyimide Solid wasteg · -60% / +100%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of inert waste, sanitary landfill
Notes
5% yield loss; inert cured material
Uncertainty
-60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Spent catalyst (from ODA synthesis) Solid wasteg · -50% / +150%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Background data
ecoinvent 3.12 treatment route
Background dataset
market for precious metal from electronics scrap, in anode slime
Notes
Pd/C catalyst traces from the ODA hydrogenation step, sent for palladium reclaim and linked to the precious-metal-from-electronics-scrap recovery market. The catalyst this waste comes from is not bought anywhere in this dataset, and no public loading or service life was found to build a purchase from. Where the step that consumes it belongs is itself unresolved: this dataset buys the diamine as a raw material and also charges electricity for the diamine synthesis and hydrogenation, so the boundary this waste sits on has not been settled. The discard is reported and the purchase behind it is left as a stated gap. The split between the palladium and its carbon support is also unstated, so the row is not a palladium quantity.
Uncertainty
-50% / +150% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Distillation residue Solid wasteg · -60% / +100%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
From NMP recovery
Uncertainty
-60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g

Emissions to air

2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

NMP (fugitive) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Compartment
Air (non-urban air or from high stacks)
Formula
C5H9NO
CAS number
872-50-4
ecoinvent 3.12 elementary flow
NMVOC, non-methane volatile organic compounds
Notes
Solvent losses during processing and drying
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
VOC (unspecified) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Compartment
Air (non-urban air or from high stacks)
ecoinvent 3.12 elementary flow
NMVOC, non-methane volatile organic compounds
Notes
Trace organics from cure process
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

1 elementary flow released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

NMP traces Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
  • No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • IntechOpen - BPDA-PDA Polyimide
  • Springer 2025 - LIG LCA study
Compartment
Water (surface water)
Formula
C5H9NO
ecoinvent 3.12 elementary flow
Not stated
Notes
Trace solvent in wastewater
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (2)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • Neither monomer has a dataset of its own. The dianhydride is represented by phthalic anhydride scaled for its extra oxidation sites and the diamine by aniline, so the upstream burden of the two largest material rows describes chemically similar but different molecules.
  • The imidization cure is inventoried as electricity only. Chemical-industry process steam cannot reach the cure temperature this route states, so it is not carried as a second heat carrier for that step.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate synthesis; proxied upstream for monomers

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol