Overview
- Technology
- Two-step polycondensation of PMDA and ODA
- Geography
- Global
System boundary
The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.
Data quality and references
Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.
- Sampling procedure
- Published polyimide synthesis literature for the polycondensation and imidization route and a recent life cycle study of the field. Monomer ratios and condensation water are stoichiometric; process energy is a proxy estimate and the upstream monomers are represented by chemically similar proxies.
- Coverage status
- Partial
- Pedigree-scored source files
- Not stated
- Dataset sources
-
- Stoichiometric calculation
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Proxy estimate
Technosphere inputs
9 flows. Quantities are not published; they ship with the dataset on Circa.
PMDA (Pyromellitic dianhydride) Materialkg · -5% / +8.3%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Background data
- proxy-mapped
- Background dataset
- phthalic anhydride
- Notes
- CarbonMinds dataset available (Fair quality); ecoinvent fallback via phthalic anhydride proxy
- Uncertainty
- -5% / +8.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
ODA (4,4'-Oxydianiline) Materialkg · -5.5% / +9.1%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Background data
- proxy-mapped
- Background dataset
- aniline
- Notes
- Not in ecoinvent; proxied via aniline + synthesis
- Uncertainty
- -5.5% / +9.1% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
NMP solvent Materialkg · -50% / +100%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Background data
- ecoinvent 3.12
- Background dataset
- N-methyl-2-pyrrolidone
- Notes
- Solvent for the polyamic-acid synthesis, distilled and returned to the next batch. This row is the non-recoverable make-up, which is what the process consumes.
- Uncertainty
- -50% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Electricity, PMDA synthesis proxy, Global (GLO) ElectricitykWh · -33.3% / +66.7%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- PMDA oxidation reaction. scaled from the phthalic anhydride basis
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, ODA synthesis, Global (GLO) ElectricitykWh · -25% / +50%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- ODA multi-step synthesis + hydrogenation. Condensation + nitro reduction
- Uncertainty
- -25% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, PAA polymerization, Global (GLO) ElectricitykWh · -33.3% / +66.7%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Mixing, cooling, nitrogen purge. Room temperature reaction
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, thermal imidization, Global (GLO) ElectricitykWh · -33.3% / +66.7%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Heating to 300-400°C for cure. Major energy consumer; depends on batch size
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, solvent recovery, Global (GLO) ElectricitykWh · -40% / +60%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- NMP distillation and recovery
- Uncertainty
- -40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Fresh water WaterL · -33.3% / +55.6%
- Derivation basis
-
- Water demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- tap water
- Uncertainty
- -33.3% / +55.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Outputs and waste
Wastewater to treatment WastewaterL · -42.9% / +71.4%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Background data
- carried, no background dataset
- Background dataset
- wastewater, average
- Uncertainty
- -42.9% / +71.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Off-spec polyimide Solid wasteg · -60% / +100%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of inert waste, sanitary landfill
- Notes
- 5% yield loss; inert cured material
- Uncertainty
- -60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Spent catalyst (from ODA synthesis) Solid wasteg · -50% / +150%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- market for precious metal from electronics scrap, in anode slime
- Notes
- Pd/C catalyst traces from the ODA hydrogenation step, sent for palladium reclaim and linked to the precious-metal-from-electronics-scrap recovery market. The catalyst this waste comes from is not bought anywhere in this dataset, and no public loading or service life was found to build a purchase from. Where the step that consumes it belongs is itself unresolved: this dataset buys the diamine as a raw material and also charges electricity for the diamine synthesis and hydrogenation, so the boundary this waste sits on has not been settled. The discard is reported and the purchase behind it is left as a stated gap. The split between the palladium and its carbon support is also unstated, so the row is not a palladium quantity.
- Uncertainty
- -50% / +150% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Distillation residue Solid wasteg · -60% / +100%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- From NMP recovery
- Uncertainty
- -60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Emissions to air
2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
NMP (fugitive) Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- C5H9NO
- CAS number
- 872-50-4
- ecoinvent 3.12 elementary flow
- NMVOC, non-methane volatile organic compounds
- Notes
- Solvent losses during processing and drying
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
VOC (unspecified) Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Compartment
- Air (non-urban air or from high stacks)
- ecoinvent 3.12 elementary flow
- NMVOC, non-methane volatile organic compounds
- Notes
- Trace organics from cure process
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Emissions to water
1 elementary flow released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
NMP traces Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
- No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- IntechOpen - BPDA-PDA Polyimide
- Springer 2025 - LIG LCA study
- Compartment
- Water (surface water)
- Formula
- C5H9NO
- ecoinvent 3.12 elementary flow
- Not stated
- Notes
- Trace solvent in wastewater
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Flows not quantified
No flows are recorded for this dataset without a quantity.
Limitations and unquantified flows (2)
Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.
- Neither monomer has a dataset of its own. The dianhydride is represented by phthalic anhydride scaled for its extra oxidation sites and the diamine by aniline, so the upstream burden of the two largest material rows describes chemically similar but different molecules.
- The imidization cure is inventoried as electricity only. Chemical-industry process steam cannot reach the cure temperature this route states, so it is not carried as a second heat carrier for that step.
The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.
Boundary declared by this dataset
Gate-to-gate synthesis; proxied upstream for monomers
Database-wide boundary policy — applies to every REEL dataset
These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.
- Use phase
- Product operation is outside the cradle-to-gate scope.
- End-of-life treatment
- Recycling and disposal are outside the cradle-to-gate scope.
- Distribution and retail
- The gate is a finished component ready for integration into a higher-level assembly.
- Inbound transport of raw materials
- Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
- Returnable shipping containers
- Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
- Photomask fabrication
- A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
- Employee transport, administration and R&D overhead
- Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
- Capital goods
- Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
- Precious metal recovery credits
- Scrap recovery credits for precious metals are excluded pending data availability.
- Wafer reclaim
- Test wafers and scrap are outside the system boundary.
Inside the boundary, linked rather than modelled
- Silicon ingot growth and wafer slicing
- Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
- Freight between production stages
- Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.
Cut-off criteria
A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.
Included regardless of the cut-off
- Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
- Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
- Volatile organics (photoresist solvents, PGMEA) - air quality
- Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
- Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol
Not stated