Overview
- Technology
- Borohydride reduction of germanium dioxide
- Geography
- Global
System boundary
The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.
Data quality and references
Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.
- Sampling procedure
- Industrial-chemistry reference works on germanium compounds for the borohydride-reduction route and stoichiometric calculation for the mass balance; no producer-specific data is public, so process energy is estimated by analogy with silane production.
- Coverage status
- Partial
- Pedigree-scored source files
- Not stated
- Dataset sources
-
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Analogous to silane (SiH4) production
- Stoichiometric calculation
Technosphere inputs
7 flows. Quantities are not published; they ship with the dataset on Circa.
Germanium dioxide Materialkg · -11.4% / +14.3%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Background data
- proxy-mapped
- Background dataset
- gallium, high-grade
- Notes
- Ge from zinc refining byproduct or coal fly ash
- Uncertainty
- -11.4% / +14.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Sodium borohydride Materialkg · -18.8% / +25%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Background data
- proxy-mapped
- Background dataset
- sodium hydroxide, without water, in 50% solution state
- Notes
- Excess ensures complete reduction
- Uncertainty
- -18.8% / +25% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Solvent (diglyme or water) Materialkg · -33.3% / +66.7%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Background data
- proxy-mapped
- Background dataset
- diethylene glycol
- Notes
- Reaction medium, recovered between batches. This row is the non-recoverable make-up, which is what the process consumes.
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Electricity, Global (GLO) ElectricitykWh · -30% / +60%
- Derivation basis
-
- Estimated from analogous hydride processes
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Synthesis, purification, compression
- Uncertainty
- -30% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Fresh water WaterL · -41.2% / +76.5%
- Derivation basis
-
- Water demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- tap water
- Uncertainty
- -41.2% / +76.5% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Nitrogen (N2) Process gaskg · -40% / +100%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- nitrogen, liquid
- Notes
- Inert atmosphere for handling pyrophoric material
- Uncertainty
- -40% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Argon (Ar) Process gaskg · -60% / +100%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- argon, liquid
- Notes
- Purging and blanketing
- Uncertainty
- -60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Outputs and waste
Wastewater to treatment WastewaterL · -46.7% / +66.7%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Background data
- carried, no background dataset
- Background dataset
- wastewater, average
- Uncertainty
- -46.7% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Distillation residue Solid wasteg · -50% / +150%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- Germanium recovery
- Notes
- Heavy germanium compounds from the distillation bottoms, sent for germanium reclaim. ecoinvent 3.12 publishes no germanium-scrap or germanium-reclamation market, so the row is linked to a generic metal-bearing sludge recovery service and that substitution is declared on the row: what the link represents is the handling of a metal-bearing residue by a recovery smelter, not any germanium content, and a reader must not take it as a supply of secondary germanium. Under the recyclable-byproduct cut-off convention the reclaim burden belongs to the next product system and no credit is taken here. The missing metal-specific dataset remains a declared gap.
- Uncertainty
- -50% / +150% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Scrubber sludge Solid wasteg · -50% / +200%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- Germanium recovery
- Notes
- Germanium dioxide formed when fugitive germane ignites, collected in the scrubber and sent for germanium reclaim. Same treatment and same cut-off as the distillation residue: no germanium reclamation market exists in ecoinvent 3.12, so the row is linked to the same generic metal-bearing sludge recovery service as a declared substitution, carries no germanium content of its own and takes no credit.
- Uncertainty
- -50% / +200% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Spent solvent Solid wasteg · -33.3% / +66.7%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- Distillation bottoms from solvent recovery: the non-recoverable fraction of the working charge, equal to the make-up bought on the input side.
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Emissions to air
2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Germane Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
- No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link
No source is attached to this row.
- Source citations
- Not stated
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- GeH4
- CAS number
- 7803-62-5
- ecoinvent 3.12 elementary flow
- Not stated
- Notes
- Pyrophoric; fugitives ignite and convert to GeO2
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Hydrogen Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- H2
- CAS number
- 1333-74-0
- ecoinvent 3.12 elementary flow
- Hydrogen
- Notes
- From side reactions and purging
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Emissions to water
2 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Borate Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Compartment
- Water (surface water)
- Formula
- BO2-
- CAS number
- 11129-12-7
- ecoinvent 3.12 elementary flow
- Borate
- Notes
- From NaBO2 byproduct dissolution
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Sodium Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
- Ullmann's Encyclopedia - Germanium
- Compartment
- Water (surface water)
- Formula
- Na+
- CAS number
- 17341-25-2
- ecoinvent 3.12 elementary flow
- Sodium I
- Notes
- From borohydride and metaborate
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Flows not quantified
No flows are recorded for this dataset without a quantity.
Limitations and unquantified flows (3)
Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.
- About a fifth of the germanium entering as germanium dioxide is not carried by any output flow, even treating both germanium-bearing residues as pure metal. It is the loss implied by the stated yield range, and no public source splits it into named streams.
- The reducing agent is charged at a large deliberate excess over stoichiometry, so roughly a third of the boron and the sodium it brings in has no output flow. The excess decomposes in the aqueous medium; only part of it reaches the borate, sodium and hydrogen rows.
- ProxyNo background dataset for germanium dioxide is available, so it is linked to the semiconductor-grade gallium market as a proxy, so the upstream burden of the largest material row describes a different element.
The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.
Boundary declared by this dataset
Gate-to-gate GeH4 synthesis from GeO2 + NaBH4
Database-wide boundary policy — applies to every REEL dataset
These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.
- Use phase
- Product operation is outside the cradle-to-gate scope.
- End-of-life treatment
- Recycling and disposal are outside the cradle-to-gate scope.
- Distribution and retail
- The gate is a finished component ready for integration into a higher-level assembly.
- Inbound transport of raw materials
- Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
- Returnable shipping containers
- Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
- Photomask fabrication
- A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
- Employee transport, administration and R&D overhead
- Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
- Capital goods
- Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
- Precious metal recovery credits
- Scrap recovery credits for precious metals are excluded pending data availability.
- Wafer reclaim
- Test wafers and scrap are outside the system boundary.
Inside the boundary, linked rather than modelled
- Silicon ingot growth and wafer slicing
- Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
- Freight between production stages
- Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.
Cut-off criteria
A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.
Included regardless of the cut-off
- Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
- Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
- Volatile organics (photoresist solvents, PGMEA) - air quality
- Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
- Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol
Not stated