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Overview

General comment

Not stated

Technology
Borohydride reduction of germanium dioxide
Geography
Global

System boundary

System boundary - Germane (GeH4)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Germane (GeH4)DECLARED BOUNDARYGate-to-gate GeH4 synthesis from GeO2 +NaBH4ENTERING FLOWSElectricityWaterProcess gasesMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTGermaneNot stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

Download this figure (SVG)

Data quality and references

Composite DQI 1.7 Very good
Reliability
2.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Industrial-chemistry reference works on germanium compounds for the borohydride-reduction route and stoichiometric calculation for the mass balance; no producer-specific data is public, so process energy is estimated by analogy with silane production.
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
  • Analogous to silane (SiH4) production
  • Stoichiometric calculation

Technosphere inputs

7 flows. Quantities are not published; they ship with the dataset on Circa.

Germanium dioxide Materialkg · -11.4% / +14.3%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Background data
proxy-mapped
Background dataset
gallium, high-grade
Notes
Ge from zinc refining byproduct or coal fly ash
Uncertainty
-11.4% / +14.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Sodium borohydride Materialkg · -18.8% / +25%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Background data
proxy-mapped
Background dataset
sodium hydroxide, without water, in 50% solution state
Notes
Excess ensures complete reduction
Uncertainty
-18.8% / +25% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Solvent (diglyme or water) Materialkg · -33.3% / +66.7%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Background data
proxy-mapped
Background dataset
diethylene glycol
Notes
Reaction medium, recovered between batches. This row is the non-recoverable make-up, which is what the process consumes.
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, Global (GLO) ElectricitykWh · -30% / +60%
Derivation basis
  • Estimated from analogous hydride processes

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Synthesis, purification, compression
Uncertainty
-30% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · -41.2% / +76.5%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-41.2% / +76.5% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Nitrogen (N2) Process gaskg · -40% / +100%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
nitrogen, liquid
Notes
Inert atmosphere for handling pyrophoric material
Uncertainty
-40% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Argon (Ar) Process gaskg · -60% / +100%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
argon, liquid
Notes
Purging and blanketing
Uncertainty
-60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg

Outputs and waste

Wastewater to treatment WastewaterL · -46.7% / +66.7%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-46.7% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Distillation residue Solid wasteg · -50% / +150%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Background data
ecoinvent 3.12 treatment route
Background dataset
Germanium recovery
Notes
Heavy germanium compounds from the distillation bottoms, sent for germanium reclaim. ecoinvent 3.12 publishes no germanium-scrap or germanium-reclamation market, so the row is linked to a generic metal-bearing sludge recovery service and that substitution is declared on the row: what the link represents is the handling of a metal-bearing residue by a recovery smelter, not any germanium content, and a reader must not take it as a supply of secondary germanium. Under the recyclable-byproduct cut-off convention the reclaim burden belongs to the next product system and no credit is taken here. The missing metal-specific dataset remains a declared gap.
Uncertainty
-50% / +150% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Scrubber sludge Solid wasteg · -50% / +200%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Background data
ecoinvent 3.12 treatment route
Background dataset
Germanium recovery
Notes
Germanium dioxide formed when fugitive germane ignites, collected in the scrubber and sent for germanium reclaim. Same treatment and same cut-off as the distillation residue: no germanium reclamation market exists in ecoinvent 3.12, so the row is linked to the same generic metal-bearing sludge recovery service as a declared substitution, carries no germanium content of its own and takes no credit.
Uncertainty
-50% / +200% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Spent solvent Solid wasteg · -33.3% / +66.7%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
Distillation bottoms from solvent recovery: the non-recoverable fraction of the working charge, equal to the make-up bought on the input side.
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g

Emissions to air

2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Germane Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
  • No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link

No source is attached to this row.

Source citations
Not stated
Compartment
Air (non-urban air or from high stacks)
Formula
GeH4
CAS number
7803-62-5
ecoinvent 3.12 elementary flow
Not stated
Notes
Pyrophoric; fugitives ignite and convert to GeO2
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Hydrogen Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Compartment
Air (non-urban air or from high stacks)
Formula
H2
CAS number
1333-74-0
ecoinvent 3.12 elementary flow
Hydrogen
Notes
From side reactions and purging
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

2 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Borate Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Compartment
Water (surface water)
Formula
BO2-
CAS number
11129-12-7
ecoinvent 3.12 elementary flow
Borate
Notes
From NaBO2 byproduct dissolution
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Sodium Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Germanium and Germanium Compounds
  • Ullmann's Encyclopedia - Germanium
Compartment
Water (surface water)
Formula
Na+
CAS number
17341-25-2
ecoinvent 3.12 elementary flow
Sodium I
Notes
From borohydride and metaborate
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (3)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • About a fifth of the germanium entering as germanium dioxide is not carried by any output flow, even treating both germanium-bearing residues as pure metal. It is the loss implied by the stated yield range, and no public source splits it into named streams.
  • The reducing agent is charged at a large deliberate excess over stoichiometry, so roughly a third of the boron and the sodium it brings in has no output flow. The excess decomposes in the aqueous medium; only part of it reaches the borate, sodium and hydrogen rows.
  • ProxyNo background dataset for germanium dioxide is available, so it is linked to the semiconductor-grade gallium market as a proxy, so the upstream burden of the largest material row describes a different element.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate GeH4 synthesis from GeO2 + NaBH4

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol