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Overview

General comment

Not stated

Technology
Carbon tetrachloride fluorination via Swarts-type halogen exchange
Geography
Global

System boundary

System boundary - Carbon tetrafluoride (CF4)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Carbon tetrafluoride (CF4)DECLARED BOUNDARYGate-to-gate CF4 synthesis from carbontetrachloride (CCl4) + HFENTERING FLOWSElectricityWaterMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTCarbon tetrafluorideNot stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

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Data quality and references

Composite DQI 1.7 Very good
Reliability
2.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Industrial-chemistry reference works describing the halogen-exchange fluorination route, published climate-assessment tables for substance properties, stoichiometric route calculation
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
  • Stoichiometric calculation

Technosphere inputs

6 flows. Quantities are not published; they ship with the dataset on Circa.

Carbon tetrachloride Materialkg · -2.8% / +5.6%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
ecoinvent 3.12
Background dataset
carbon tetrachloride
Notes
A small stoichiometric excess is an ESTIMATE; excess and unconverted intermediates are recovered/recycled in the halogen-exchange loop.
Uncertainty
-2.8% / +5.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Hydrogen fluoride (anhydrous) Materialkg · -4.8% / +9.9%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
ecoinvent 3.12
Background dataset
hydrogen fluoride
Notes
A small excess is an ESTIMATE; excess HF recovered/recycled in process. Basis: the balanced route requires 4 HF per CF4.
Uncertainty
-4.8% / +9.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Antimony pentafluoride catalyst Materialkg · -60% / +100%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
proxy-mapped
Background dataset
antimony
Notes
Catalyst makeup; mostly recycled in process
Uncertainty
-60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Hydrated lime (wastewater treatment) Materialkg · -74.3% / +148.6%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
proxy-mapped
Background dataset
calcium carbonate, precipitated
Notes
Precipitant for the fluoride captured in the off-gas scrubber. It supplies the calcium in the calcium fluoride sludge this dataset ships.
Uncertainty
-74.3% / +148.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, Global (GLO) ElectricitykWh · ±28.6%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Heating, compression, purification
Uncertainty
±28.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · -38.5% / +84.6%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-38.5% / +84.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L

Outputs and waste

Wastewater to treatment WastewaterL · -40% / +60%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Spent catalyst Solid wasteg · -60% / +100%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, underground deposit
Notes
Antimony halide catalyst, regenerated in the loop and periodically purged. An inorganic metal-halide residue, routed to controlled inorganic disposal.
Uncertainty
-60% / +100% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Calcium fluoride sludge Solid wasteg · -75.7% / +148.6%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of inert waste, sanitary landfill
Notes
Precipitated from the fluoride in the treated wastewater; the calcium comes from the hydrated-lime input row.
Uncertainty
-75.7% / +148.6% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Purification residue Solid wasteg · -66.7% / +166.7%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
Heavy organics from distillation
Uncertainty
-66.7% / +166.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g

Emissions to air

3 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Carbon tetrafluoride Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

No source is attached to this row.

Source citations
Not stated
Compartment
Air (non-urban air or from high stacks)
Formula
CF4
CAS number
75-73-0
ecoinvent 3.12 elementary flow
Tetrafluoromethane
Notes
Fugitive from process; target for reduction due to high GWP
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Hydrogen fluoride Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Compartment
Air (non-urban air or from high stacks)
Formula
HF
CAS number
7664-39-3
ecoinvent 3.12 elementary flow
Hydrogen fluoride
Notes
Fugitive from handling
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Carbon tetrachloride Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Compartment
Air (non-urban air or from high stacks)
Formula
CCl4
CAS number
56-23-5
ecoinvent 3.12 elementary flow
Carbon tetrachloride
Notes
Unreacted feedstock fugitive.
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

2 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Chloride ion Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Compartment
Water (surface water)
Formula
Cl-
CAS number
16887-00-6
ecoinvent 3.12 elementary flow
Chloride
Notes
From HCl scrubbing
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Fluoride ion Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
  • Ullmann's Encyclopedia of Industrial Chemistry - Fluorine Compounds, Organic (Siegemund, Schwertfeger, Feiring, Smart, Behr, Vogel, McKusick, 2002)
  • IPCC AR6 - Table 7.SM.7
Compartment
Water (surface water)
Formula
F-
CAS number
16984-48-8
ecoinvent 3.12 elementary flow
Fluoride
Notes
Dissolved fluoride remaining after lime precipitation of the HF scrubber water. The bulk of the captured fluoride leaves as the calcium fluoride sludge instead.
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (1)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • Both feedstocks are authored with a small process loss over stoichiometry. That loss has no output flow of its own: the fugitive, wastewater and residue rows account for only part of it.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate CF4 synthesis from carbon tetrachloride (CCl4) + HF

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol