Overview
- Technology
- Two-step process: TFE synthesis then dimerization
- Geography
- Global
System boundary
The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.
Data quality and references
Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.
- Sampling procedure
- Industrial-chemistry reference works and fluoropolymer production literature for the tetrafluoroethylene route, greenhouse-gas inventory guidelines for substance properties, stoichiometric route calculation
- Coverage status
- Partial
- Pedigree-scored source files
- Not stated
- Dataset sources
-
- Stoichiometric calculation
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- Fluoropolymer production literature
- IPCC Guidelines
Technosphere inputs
9 flows. Quantities are not published; they ship with the dataset on Circa.
Chlorodifluoromethane (R-22) Materialkg
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
- No corresponding ecoinvent dataset or flow was identified for this entry; its background is carried by the mapped dataset named on this row
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- CarbonMinds
- Background dataset
- difluorochloromethane
- Notes
- ALTERNATIVE procurement route (buy pre-made R-22) - quantity zeroed, NOT counted. The modelled route synthesizes R-22 on-site from the chloroform + HF rows below plus the R-22-synthesis electricity row this dataset publishes. Carrying both the pre-made R-22 mass AND its synthesis feedstocks would double-count the material chain, so exactly one route is counted. Row retained at zero to document the alternative route and its CarbonMinds link for users who source R-22 externally. R-22 is HCFC; controlled under Montreal Protocol.
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- kg
Hydrogen fluoride (for R-22) Materialkg · -8.6% / +12.9%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- ecoinvent 3.12
- Background dataset
- hydrogen fluoride
- Notes
- Available in ecoinvent
- Uncertainty
- -8.6% / +12.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Chloroform Materialkg · -7.6% / +10.7%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- ecoinvent 3.12
- Background dataset
- chloroform
- Notes
- Available in ecoinvent. The chloroform feed is set by carbon balance on the on-site R-22 route: it must supply enough carbon for the R-22 the route consumes, which fixes the feed well above what a purchased-R-22 construction would imply.
- Uncertainty
- -7.6% / +10.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Hydrated lime (wastewater treatment) Materialkg · -59.8% / +142.5%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
The sources for this row are listed below.
- Source citations (dataset-level)
-
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- proxy-mapped
- Background dataset
- calcium carbonate, precipitated
- Notes
- Precipitant for the fluoride in the process wastewater. It supplies the calcium in the calcium fluoride sludge this dataset ships.
- Uncertainty
- -59.8% / +142.5% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kg
Electricity, R-22 synthesis, Global (GLO) ElectricitykWh · -33.3% / +66.7%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Vapor-phase fluorination of chloroform
- Uncertainty
- -33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, C4F8 dimerization, Global (GLO) ElectricitykWh · ±50%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Dimerization reaction
- Uncertainty
- ±50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Electricity, purification, Global (GLO) ElectricitykWh · ±50%
- Derivation basis
-
- Energy demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- electricity, medium voltage
- Notes
- Distillation to electronic grade
- Uncertainty
- ±50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- kWh
Natural gas heat (pyrolysis heating) ThermalMJ · -37.5% / +50%
- Derivation basis
-
- The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- heat production, natural gas, at industrial furnace low-NOx >100kW
- Notes
- High-temperature pyrolysis furnace. – the linked activity is a natural-gas industrial furnace, so its burden covers burning the fuel as well as supplying it. The quantity is the heat the furnace delivers, obtained from the fuel demand through the fuel's lower heating value and the furnace's fuel-per-heat ratio. The air emissions in this dataset are fugitive releases only and carry no combustion products, so nothing is counted twice.
- Uncertainty
- -37.5% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- MJ
Fresh water WaterL · -33.3% / +50%
- Derivation basis
-
- Water demand specified by the model.
No source is attached to this row.
- Source citations
- Not stated
- Background data
- ecoinvent 3.12
- Background dataset
- tap water
- Uncertainty
- -33.3% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Outputs and waste
Wastewater to treatment WastewaterL · -40% / +50%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- carried, no background dataset
- Background dataset
- wastewater, average
- Uncertainty
- -40% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- L
Heavy ends and oligomers Solid wasteg · -40% / +60%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- TFE polymerization byproducts (PTFE-like)
- Uncertainty
- -40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Calcium fluoride sludge Solid wasteg · -59.8% / +141.3%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of inert waste, sanitary landfill
- Notes
- Precipitated from the fluoride in the treated wastewater; the calcium comes from the hydrated-lime input row.
- Uncertainty
- -59.8% / +141.3% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Off-spec fluorocarbons and unreacted HF to abatement Solid wasteg · -44.6% / +66.2%
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Background data
- ecoinvent 3.12 treatment route
- Background dataset
- treatment of hazardous waste, hazardous waste incineration, with energy recovery
- Notes
- Unreacted hydrogen fluoride and off-spec fluorocarbons from the pyrolysis and dimerization steps, collected and thermally destroyed. The amount is the residue the gate balance on this route leaves once the product, the co-product, the other waste streams and the reported releases are accounted for; it is not a measured stream. The split between species is not resolved, and neither is the fate of the water formed when the treatment lime neutralises the captured acid.
- Uncertainty
- -44.6% / +66.2% around the published quantity. The bounds themselves ship with the dataset on Circa.
- Unit
- g
Emissions to air
3 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Octafluorocyclobutane (fugitive) Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- C4F8
- CAS number
- 115-25-3
- ecoinvent 3.12 elementary flow
- Tetrafluoromethane
- Notes
- Minor fugitive losses during handling; Proxied to CF4 (Tetrafluoromethane) for ecoinvent linking. The two substances are not equivalent: this one has the substantially greater warming effect of the pair, so any characterization performed through this proxy link understates it. Use the substance's own factor rather than the proxy's.
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Tetrafluoroethylene Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
- No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- C2F4
- CAS number
- 116-14-3
- ecoinvent 3.12 elementary flow
- Not stated
- Notes
- Unreacted tetrafluoroethylene from the pyrolysis step. The reactor off-gas passes through treatment, and the sources behind this dataset do not fix where in that chain the quantity reported here was measured. The treatment position is unresolved: this row states neither that the amount escaped the abatement nor that it entered it.
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Hydrogen chloride Emission to airg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Compartment
- Air (non-urban air or from high stacks)
- Formula
- HCl
- CAS number
- 7647-01-0
- ecoinvent 3.12 elementary flow
- Hydrochloric acid
- Notes
- Fugitive from R-22 synthesis; most recovered
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Emissions to water
2 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.
Chloride ion Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Compartment
- Water (surface water)
- Formula
- Cl-
- CAS number
- 16887-00-6
- ecoinvent 3.12 elementary flow
- Chloride
- Notes
- From HCl scrubbing; after recovery
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Fluoride ion Emission to waterg
- Derivation basis
-
- The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
The sources below are this dataset's own bibliography. They are not tied to this row.
- Source citations (dataset-level)
- Inherited from this dataset's own bibliography, not tied to this row:
- Kirk-Othmer Encyclopedia - Fluorine Compounds, Organic
- IPCC Guidelines
- Compartment
- Water (surface water)
- Formula
- F-
- CAS number
- 16984-48-8
- ecoinvent 3.12 elementary flow
- Fluoride
- Notes
- Dissolved fluoride remaining after lime precipitation. The bulk of the captured fluoride leaves as the calcium fluoride sludge instead.
- Uncertainty
- A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
- Unit
- g
Flows not quantified
No flows are recorded for this dataset without a quantity.
Limitations and unquantified flows (3)
Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.
- The off-spec fluorocarbon and unreacted-hydrogen-fluoride row is not broken down by substance. It carries the declared process loss that the product, the recovered acid and the measured emissions do not account for; no public source splits it into named species, so it ships as one abated stream.
- A small remainder of the fluorine and the carbon entering the process is still not carried by any output flow once that stream is counted.
- The pyrolysis furnace is inventoried as fired heat only. Its own fan, blower and gas-handling electricity is not modelled separately, so the electricity figure covers the fluorination, dimerization and purification steps alone.
The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.
Boundary declared by this dataset
Gate-to-gate from CHCl3/HF to C4F8
Database-wide boundary policy — applies to every REEL dataset
These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.
- Use phase
- Product operation is outside the cradle-to-gate scope.
- End-of-life treatment
- Recycling and disposal are outside the cradle-to-gate scope.
- Distribution and retail
- The gate is a finished component ready for integration into a higher-level assembly.
- Inbound transport of raw materials
- Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
- Returnable shipping containers
- Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
- Photomask fabrication
- A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
- Employee transport, administration and R&D overhead
- Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
- Capital goods
- Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
- Precious metal recovery credits
- Scrap recovery credits for precious metals are excluded pending data availability.
- Wafer reclaim
- Test wafers and scrap are outside the system boundary.
Inside the boundary, linked rather than modelled
- Silicon ingot growth and wafer slicing
- Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
- Freight between production stages
- Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.
Cut-off criteria
A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.
Included regardless of the cut-off
- Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
- Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
- Volatile organics (photoresist solvents, PGMEA) - air quality
- Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
- Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol
Not stated