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Overview

General comment

Not stated

Technology
ONE counted route: hydrofluorination of butadiene followed by dehydrofluorination of the saturated fluorobutane intermediate. The dehalogenation route is documented below as an alternative and its rows are zeroed, so exactly one route is inventoried.
Geography
Global

System boundary

System boundary - Hexafluoro-1,3-butadiene (C4F6)System boundary figure: identity, gate in, entering flows, the dashed system boundary and the unit processes inside it, the reference product, emissions and waste, and below it the flows that are recorded but not quantified. No inventory quantities.Hexafluoro-1,3-butadiene (C4F6)DECLARED BOUNDARYGate-to-gate synthesis via the butadiene +hydrogen fluoride routeENTERING FLOWSElectricityWaterMaterialsSYSTEM BOUNDARYAGGREGATED PRODUCTION MODELModelled as one production operation.This dataset models the production of this material as a single aggregated operation at the supplier plant.Its inputs and outputs are recorded against that operation rather than a step-by-step recipe.REFERENCE PRODUCTHexafluoro-1,3-butadieneNot stated in the dataset recordEMISSIONS AND WASTEEmissions to airEmissions to waterWaste routesRECORDED BUT NOT QUANTIFIEDExclusions not yet characterisedNo exclusion record was found for this datasetNOT CHARACTERISEDsystem boundaryreference flowentering flowemission / waste

The figure groups this dataset's unit processes by class. It is not a count of manufacturing steps — each process runs over as many passes as the flow requires, and those pass counts ship with the dataset.

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Data quality and references

Composite DQI 2.1 Good
Reliability
5.0
Completeness
1.0
Temporal
1.0
Geographic
2.0
Technological
4.0

Pedigree scores follow the ecoinvent data-quality matrix: 1 is the best attainable, 5 the weakest. The composite is their aggregate.

Sampling procedure
Synthesis-route patents from fluorinated-gas producers, greenhouse-gas inventory guidelines for substance properties, and stoichiometric route calculation. Public production data for this gas is sparse, so reaction energy is carried across from the octafluorocyclobutane dataset.
Coverage status
Partial
Pedigree-scored source files
Not stated
Dataset sources
  • Stoichiometric calculation
  • Proxy from C4F8 production
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines

Technosphere inputs

7 flows. Quantities are not published; they ship with the dataset on Circa.

Butadiene (or derivative) Materialkg · -12.5% / +25%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
ecoinvent 3.12
Background dataset
butadiene
Notes
Available in ecoinvent
Uncertainty
-12.5% / +25% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Hydrogen fluoride Materialkg · -26% / +40%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
ecoinvent 3.12
Background dataset
hydrogen fluoride
Notes
Available in ecoinvent
Uncertainty
-26% / +40% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Zinc (dehalogenation route) Materialkg
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
ecoinvent 3.12
Background dataset
zinc
Notes
ALTERNATIVE ROUTE - quantity zeroed, NOT counted. Zinc-mediated dehalogenation is one of the published ways to make this gas, but it needs a chlorinated precursor that this inventory does not buy, and the counted route is the hydrogen-fluoride one. Row retained at zero to document the alternative and its ecoinvent link for users modelling it.
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
kg
Hydrated lime (wastewater treatment) Materialkg · -50.6% / +148.9%
Derivation basis
  • The model specifies this input from the production route, either from the chemistry of the reaction or from the allowance the route sets for it. It also states the excess the route uses and the share it recovers for reuse.

The sources for this row are listed below.

Source citations (dataset-level)
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
proxy-mapped
Background dataset
calcium carbonate, precipitated
Notes
Precipitant for the fluoride in the process wastewater. It supplies the calcium in the calcium fluoride sludge this dataset ships.
Uncertainty
-50.6% / +148.9% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kg
Electricity, fluorination and synthesis, Global (GLO) ElectricitykWh · -40% / +50%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Fluorination reaction and temperature control. Proxy from C4F8
Uncertainty
-40% / +50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Electricity, purification, Global (GLO) ElectricitykWh · -40% / +60%
Derivation basis
  • Energy demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
electricity, medium voltage
Notes
Distillation, isomer separation. C4F6 requires careful purification
Uncertainty
-40% / +60% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
kWh
Fresh water WaterL · -33.3% / +66.7%
Derivation basis
  • Water demand specified by the model.

No source is attached to this row.

Source citations
Not stated
Background data
ecoinvent 3.12
Background dataset
tap water
Uncertainty
-33.3% / +66.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L

Outputs and waste

Wastewater to treatment WastewaterL · -28.6% / +71.4%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
carried, no background dataset
Background dataset
wastewater, average
Uncertainty
-28.6% / +71.4% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
L
Over-fluorinated products Solid wasteg · ±50%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, hazardous waste incineration, with energy recovery
Notes
C4F8 and saturated byproducts
Uncertainty
±50% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Calcium fluoride sludge Solid wasteg · -50.3% / +149.7%
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of inert waste, sanitary landfill
Notes
Precipitated from the fluoride in the treated wastewater; the calcium comes from the hydrated-lime input row.
Uncertainty
-50.3% / +149.7% around the published quantity. The bounds themselves ship with the dataset on Circa.
Unit
g
Zinc residue (dehalogenation route) Solid wasteg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Background data
ecoinvent 3.12 treatment route
Background dataset
treatment of hazardous waste, underground deposit
Notes
ALTERNATIVE ROUTE - quantity zeroed, NOT counted. A zinc metal residue is an inorganic waste, so the class is set accordingly for anyone modelling that route.
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to air

2 elementary flows released to air by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Hexafluorobutadiene (fugitive) Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.
  • No corresponding ecoinvent dataset or flow was identified for this entry, so it is published with its own quantity and no background link

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Compartment
Air (non-urban air or from high stacks)
Formula
C4F6
CAS number
685-63-2
ecoinvent 3.12 elementary flow
Not stated
Notes
Minor fugitive losses
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Hydrogen fluoride Emission to airg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Compartment
Air (non-urban air or from high stacks)
Formula
HF
CAS number
7664-39-3
ecoinvent 3.12 elementary flow
Hydrogen fluoride
Notes
Fugitive from synthesis; most captured
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Emissions to water

2 elementary flows released to water by this dataset's own operations. Quantities are not published; they ship with the dataset on Circa.

Fluoride ion Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Compartment
Water (surface water)
Formula
F-
CAS number
16984-48-8
ecoinvent 3.12 elementary flow
Fluoride
Notes
Dissolved fluoride remaining after lime precipitation. The bulk of the captured fluoride leaves as the calcium fluoride sludge instead.
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g
Chloride ion (dehalogenation route) Emission to waterg
Derivation basis
  • The model estimates this flow from the mass balance of the operation and from the share of material the operation loses.

The sources below are this dataset's own bibliography. They are not tied to this row.

Source citations (dataset-level)
Inherited from this dataset's own bibliography, not tied to this row:
  • Patent literature (Showa Denko, Air Products)
  • IPCC Guidelines
Compartment
Water (surface water)
Formula
Cl-
CAS number
16887-00-6
ecoinvent 3.12 elementary flow
Chloride
Notes
ALTERNATIVE ROUTE - quantity zeroed, NOT counted. The counted hydrogen-fluoride route brings no chlorine into the process.
Uncertainty
A minimum-maximum range is defined for this flow. Bounds ship with the dataset on Circa.
Unit
g

Flows not quantified

No flows are recorded for this dataset without a quantity.

Limitations and unquantified flows (2)

Limits this dataset declares about itself: first any limit stated in its own description, then any limit it declares flow by flow, grouped by channel. Each entry below is the model's own disclosure.

  • Most of the hydrogen displaced from the butadiene as it is fluorinated is not carried by any output flow. On the idealised route it would leave as hydrogen gas, but no public source for this gas quantifies that stream, so it is declared rather than invented.
  • Roughly a tenth of the fluorine entering as hydrogen fluoride is likewise not carried by any output flow.

The flows above are this dataset's own records. What follows are the scope rules set once for the whole database in the methodology report, repeated here so every dataset page carries them.

Boundary declared by this dataset

Gate-to-gate synthesis via the butadiene + hydrogen fluoride route

Database-wide boundary policy — applies to every REEL dataset

These boundaries are set once for the whole database, in Chapter 2 of the methodology report, and apply to this dataset wherever they are relevant to it. The excluded flows listed above are specific to this dataset.

Use phase
Product operation is outside the cradle-to-gate scope.
End-of-life treatment
Recycling and disposal are outside the cradle-to-gate scope.
Distribution and retail
The gate is a finished component ready for integration into a higher-level assembly.
Inbound transport of raw materials
Transport of purchased raw materials to the manufacturing facility is already inside the upstream "market for" datasets that users link to a background database, so it is not modelled a second time here. This does not cover freight between REEL production stages, which is modelled where a dataset authors it.
Returnable shipping containers
Where freight between production stages is modelled, the mass moved is the product itself. The shipping container (FOSB, SEMI M31) is returnable capital equipment whose per-trip share is unsourced, so its tare is excluded from the transport effort.
Photomask fabrication
A mask set's embodied burden is amortised across a high-volume production run and is not attributed per wafer. Users assessing low-volume production should add mask fabrication separately; the methodology report gives the basis for the exclusion.
Employee transport, administration and R&D overhead
Employee transportation, facility administration and R&D/pilot-production overhead are outside scope.
Capital goods
Manufacturing equipment, cleanroom construction and facility infrastructure are excluded, on the grounds of absent public data on equipment embodied energy, uncertainty in equipment lifetime and allocation, common practice in electronics LCA, and a focus on the operational inventory. Future versions may include capital goods when sufficient public data becomes available.
Precious metal recovery credits
Scrap recovery credits for precious metals are excluded pending data availability.
Wafer reclaim
Test wafers and scrap are outside the system boundary.

Inside the boundary, linked rather than modelled

Silicon ingot growth and wafer slicing
Inside the cradle-to-gate scope, but treated as upstream material inputs linked to background databases rather than modelled as REEL processes.
Freight between production stages
Where a dataset's product moves between REEL production stages - wafer fabrication to the packaging site, for example - that leg is authored as a transport service and linked to an ecoinvent freight activity. It is measured as a transport effort in tonne-kilometres, not as a mass. Route distances are authored per route class with a stated band; a lower bound of zero is a modelling statement that the two sites can be co-located, not a missing value.

Cut-off criteria

A flow is excluded from a process inventory when it contributes less than 1 % of the total mass of inputs to that unit process, or less than 1 % of its total energy input. The denominator is total process inputs, not product mass. That distinction matters in semiconductor manufacturing, where the input mass of water, chemicals and gases greatly exceeds the product mass, so the threshold removes only genuinely minor flows.

Included regardless of the cut-off

  • Perfluorocarbons (CF4, C2F6, SF6, NF3) - high GWP, EPA regulated
  • Heavy metals (Pb, Cd, Hg, Cr(VI)) - RoHS regulated, high toxicity
  • Volatile organics (photoresist solvents, PGMEA) - air quality
  • Precious metals (Au, Ag, Pd, Pt) - high embodied impacts
  • Ozone-depleting substances (legacy CFCs, HCFCs) - Montreal Protocol